Ca:cc-pVDZ               
Dunning's correlation consistent basis set
 
    3
    0    1    2
    5    4    2
   53   31    5
 
   190000.700000000012    28481.459999999999     6482.701000000000     1835.891000000000      598.724300000000      215.884100000000       84.012420000000       34.224880000000       10.024970000000        4.055920000000        1.020261000000        0.426865000000        0.063347000000   190000.700000000012    28481.459999999999     6482.701000000000     1835.891000000000      598.724300000000      215.884100000000       84.012420000000       34.224880000000       10.024970000000        4.055920000000        1.020261000000        0.426865000000        0.063347000000   190000.700000000012    28481.459999999999     6482.701000000000     1835.891000000000      598.724300000000      215.884100000000       84.012420000000       34.224880000000       10.024970000000        4.055920000000        1.020261000000        0.426865000000        0.063347000000   190000.700000000012    28481.459999999999     6482.701000000000     1835.891000000000      598.724300000000      215.884100000000       84.012420000000       34.224880000000       10.024970000000        4.055920000000        1.020261000000        0.426865000000        0.063347000000        0.026301000000
 
        0.000221450000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001718300000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.008923480000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.036301830000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.117622230000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.286043520000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.422607080000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.257743660000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.023918930000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.004952180000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001717790000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.000892090000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000245100000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000064530000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000496620000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.002628260000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.010668450000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.037135090000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.098042840000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.203426920000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.152446550000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.482794060000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.629238390000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.061648420000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.014799710000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.003610890000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000022230000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000171700000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000904520000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.003703430000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.012837500000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.034754590000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.073034910000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.061000830000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.242929280000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.487085000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.565028040000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.655743860000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.026728940000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000005310000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000041110000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000215680000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000888270000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.003058130000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.008376080000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.017410560000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.015154530000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.062079190000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.126118030000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.173606940000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.378229430000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.659646980000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
     1072.043000000000      253.843900000000       81.316260000000       30.241830000000       12.101100000000        5.022554000000        1.909220000000        0.771304000000        0.300570000000        0.076649000000     1072.043000000000      253.843900000000       81.316260000000       30.241830000000       12.101100000000        5.022554000000        1.909220000000        0.771304000000        0.300570000000        0.076649000000     1072.043000000000      253.843900000000       81.316260000000       30.241830000000       12.101100000000        5.022554000000        1.909220000000        0.771304000000        0.300570000000        0.076649000000        0.027772000000
 
        0.001981660000        0.000000000000        0.000000000000        0.000000000000
        0.016129440000        0.000000000000        0.000000000000        0.000000000000
        0.076578510000        0.000000000000        0.000000000000        0.000000000000
        0.232695940000        0.000000000000        0.000000000000        0.000000000000
        0.424452100000        0.000000000000        0.000000000000        0.000000000000
        0.373264020000        0.000000000000        0.000000000000        0.000000000000
        0.078685300000        0.000000000000        0.000000000000        0.000000000000
       -0.005999270000        0.000000000000        0.000000000000        0.000000000000
        0.002642570000        0.000000000000        0.000000000000        0.000000000000
       -0.000856940000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000648910000        0.000000000000        0.000000000000
        0.000000000000       -0.005279070000        0.000000000000        0.000000000000
        0.000000000000       -0.025811310000        0.000000000000        0.000000000000
        0.000000000000       -0.080628920000        0.000000000000        0.000000000000
        0.000000000000       -0.158465520000        0.000000000000        0.000000000000
        0.000000000000       -0.128168160000        0.000000000000        0.000000000000
        0.000000000000        0.256101030000        0.000000000000        0.000000000000
        0.000000000000        0.587240680000        0.000000000000        0.000000000000
        0.000000000000        0.303725610000        0.000000000000        0.000000000000
        0.000000000000        0.014164510000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000135950000        0.000000000000
        0.000000000000        0.000000000000        0.001094200000        0.000000000000
        0.000000000000        0.000000000000        0.005426800000        0.000000000000
        0.000000000000        0.000000000000        0.016747180000        0.000000000000
        0.000000000000        0.000000000000        0.033898630000        0.000000000000
        0.000000000000        0.000000000000        0.025311830000        0.000000000000
        0.000000000000        0.000000000000       -0.058957130000        0.000000000000
        0.000000000000        0.000000000000       -0.158761200000        0.000000000000
        0.000000000000        0.000000000000       -0.085545230000        0.000000000000
        0.000000000000        0.000000000000        0.544646650000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       10.318200000000        2.592420000000        0.761700000000        0.208380000000        0.053700000000
 
        0.032849000000        0.000000000000
        0.148192000000        0.000000000000
        0.310921000000        0.000000000000
        0.452195000000        0.000000000000
        0.000000000000        1.000000000000
 
Ca:cc-pVTZ               
Dunning's correlation consistent basis set
 
    4
    0    1    2    3
    6    5    3    1
   74   38    6    1
 
  2402654.000000000000   359789.799999999988    81878.089999999997    23190.889999999999     7565.212000000000     2730.702000000000     1064.640000000000      441.060500000000      191.726900000000       86.537740000000       39.899240000000       17.640650000000        8.359990000000        3.951330000000        1.713400000000        0.810860000000        0.360250000000        0.044840000000  2402654.000000000000   359789.799999999988    81878.089999999997    23190.889999999999     7565.212000000000     2730.702000000000     1064.640000000000      441.060500000000      191.726900000000       86.537740000000       39.899240000000       17.640650000000        8.359990000000        3.951330000000        1.713400000000        0.810860000000        0.360250000000        0.044840000000  2402654.000000000000   359789.799999999988    81878.089999999997    23190.889999999999     7565.212000000000     2730.702000000000     1064.640000000000      441.060500000000      191.726900000000       86.537740000000       39.899240000000       17.640650000000        8.359990000000        3.951330000000        1.713400000000        0.810860000000        0.360250000000        0.044840000000  2402654.000000000000   359789.799999999988    81878.089999999997    23190.889999999999     7565.212000000000     2730.702000000000     1064.640000000000      441.060500000000      191.726900000000       86.537740000000       39.899240000000       17.640650000000        8.359990000000        3.951330000000        1.713400000000        0.810860000000        0.360250000000        0.044840000000        0.081080000000        0.021430000000
 
        0.000009310000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000072390000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000380590000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001604530000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.005807800000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.018595660000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.052877760000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.130151490000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.259314710000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.361496100000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.264111600000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.057093980000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.001822000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.002111640000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.000977090000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000455810000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.000191460000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.000078740000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000002700000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000021020000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000110520000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000466660000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.001695130000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.005483460000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.015965970000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.041513840000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.092863870000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.165316570000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.176640740000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.064444220000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.510879620000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.494638040000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.087500940000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.003591010000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.002492200000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000645870000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000930000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000007250000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000038110000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000161010000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000584660000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.001895040000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.005525250000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.014470100000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.032715810000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.060031900000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.067016830000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.025936600000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.267474670000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.426972560000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.067964050000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.710205390000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.441800570000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.011869240000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000000220000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000001730000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000009100000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000038440000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000139650000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000452510000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.001320380000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.003458410000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.007836860000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.014415170000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.016216480000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.006344200000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.067406260000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.114473960000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.026344770000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.233698850000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.316075380000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.561110350000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
     4061.289000000000      962.246500000000      312.168600000000      118.714400000000       49.806700000000       22.259980000000       10.287640000000        4.861154000000        2.248773000000        1.033662000000        0.464132000000        0.067390000000     4061.289000000000      962.246500000000      312.168600000000      118.714400000000       49.806700000000       22.259980000000       10.287640000000        4.861154000000        2.248773000000        1.033662000000        0.464132000000        0.067390000000     4061.289000000000      962.246500000000      312.168600000000      118.714400000000       49.806700000000       22.259980000000       10.287640000000        4.861154000000        2.248773000000        1.033662000000        0.464132000000        0.067390000000        0.198750000000        0.025420000000
 
        0.000197990000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001732080000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.009533790000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.038390120000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.116758810000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.256268740000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.379780800000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.308293260000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.085920900000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.002120670000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001288800000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000147280000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000064550000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000564580000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.003131250000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.012740860000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.039914030000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.090504480000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.142618980000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.109809040000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.151624900000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.461764110000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.432600310000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.002528740000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000013360000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000118520000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000648720000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.002679930000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.008285130000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.019212350000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.029549840000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.024312320000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.041112300000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.104197580000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.150365370000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.598611640000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       16.946230000000        4.472120000000        1.438090000000        0.466990000000        0.141510000000        0.041640000000
 
        0.015473000000        0.000000000000        0.000000000000
        0.078874000000        0.000000000000        0.000000000000
        0.208780000000        0.000000000000        0.000000000000
        0.330213000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000
 
        0.150900000000
 
        1.000000000000
 
Ca:cc-pVQZ               
Dunning's correlation consistent basis set
 
    5
    0    1    2    3    4
    7    6    4    2    1
   79   42    7    2    1
 
  7503960.000000000000  1123486.000000000000   255663.500000000000    72416.059999999998    23626.040000000001     8529.986000000001     3327.341000000000     1380.354000000000      602.214900000000      273.887400000000      128.945100000000       62.422990000000       30.574370000000       13.855220000000        6.836204000000        3.378153000000        1.491907000000        0.721140000000        0.334152000000  7503960.000000000000  1123486.000000000000   255663.500000000000    72416.059999999998    23626.040000000001     8529.986000000001     3327.341000000000     1380.354000000000      602.214900000000      273.887400000000      128.945100000000       62.422990000000       30.574370000000       13.855220000000        6.836204000000        3.378153000000        1.491907000000        0.721140000000        0.334152000000  7503960.000000000000  1123486.000000000000   255663.500000000000    72416.059999999998    23626.040000000001     8529.986000000001     3327.341000000000     1380.354000000000      602.214900000000      273.887400000000      128.945100000000       62.422990000000       30.574370000000       13.855220000000        6.836204000000        3.378153000000        1.491907000000        0.721140000000        0.334152000000  7503960.000000000000  1123486.000000000000   255663.500000000000    72416.059999999998    23626.040000000001     8529.986000000001     3327.341000000000     1380.354000000000      602.214900000000      273.887400000000      128.945100000000       62.422990000000       30.574370000000       13.855220000000        6.836204000000        3.378153000000        1.491907000000        0.721140000000        0.334152000000        0.082382000000        0.041655000000        0.019973000000
 
        0.000002240000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000017440000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000091770000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000387680000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001411850000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.004593590000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.013597330000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.036673600000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.088720760000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.184148930000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.300742160000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.324348150000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.171957470000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.024809330000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.001034080000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001012900000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.000466780000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000186620000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.000088080000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000000650000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000005070000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000026630000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000112660000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000410300000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.001341110000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.003994040000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.010989030000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.027564470000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.062162460000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.118604760000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.174104940000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.118477140000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.194574680000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.546611310000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.381263240000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.051878530000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.002049960000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.001688090000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000220000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000001750000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000009180000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000038880000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000141380000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000463240000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.001377310000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.003807860000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.009556410000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.021831320000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.042149510000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.064628450000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.045359830000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.082498530000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.323151070000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.360634960000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.204389540000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.696100890000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.361774980000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000000050000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000000420000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000002190000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000009290000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000033740000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000110700000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000328620000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000910500000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.002280900000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.005230950000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.010083610000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.015612940000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.010883380000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.019957680000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.083488600000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.095949510000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.063957720000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.245224870000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.285846700000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
     9363.010000000000     2216.255000000000      719.759600000000      275.172800000000      116.392400000000       52.777700000000       25.131880000000       12.314160000000        6.166797000000        3.114279000000        1.519013000000        0.725435000000        0.340926000000     9363.010000000000     2216.255000000000      719.759600000000      275.172800000000      116.392400000000       52.777700000000       25.131880000000       12.314160000000        6.166797000000        3.114279000000        1.519013000000        0.725435000000        0.340926000000     9363.010000000000     2216.255000000000      719.759600000000      275.172800000000      116.392400000000       52.777700000000       25.131880000000       12.314160000000        6.166797000000        3.114279000000        1.519013000000        0.725435000000        0.340926000000        0.144000000000        0.058000000000        0.023160000000
 
        0.000046170000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000410490000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.002355670000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.010254910000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.035660350000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.099640560000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.213206260000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.331535240000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.329342630000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.154664140000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.022155260000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000551910000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000151770000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000015050000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000133610000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000770140000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.003364530000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.011866240000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.033894230000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.075143290000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.121443480000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.129220840000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.015877030000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.308536760000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.472815210000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.294102810000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000003130000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000027950000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000160030000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000704170000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.002469220000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.007118990000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.015690170000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.025785640000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.026936560000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.004855860000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.076542120000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.115544590000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.121270620000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       26.270830000000        7.307820000000        2.454980000000        0.887140000000        0.309250000000        0.103160000000        0.033740000000
 
        0.007346000000        0.000000000000        0.000000000000        0.000000000000
        0.040901000000        0.000000000000        0.000000000000        0.000000000000
        0.130065000000        0.000000000000        0.000000000000        0.000000000000
        0.244151000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
        0.488300000000        0.116500000000
 
        1.000000000000        0.000000000000
        0.000000000000        1.000000000000
 
        0.146600000000
 
        1.000000000000
 
Ca:cc-pV5Z               
Dunning's correlation consistent basis set
 
    6
    0    1    2    3    4    5
    8    7    5    3    2    1
   92   46    8    3    2    1
 
 28249600.000000000000  4250190.000000000000   975014.000000000000   277446.000000000000    90454.699999999997    32515.900000000001    12610.600000000000     5190.770000000000     2242.330000000000     1011.530000000000      475.547000000000      232.072000000000      116.874000000000       60.342700000000       31.524400000000       16.030800000000        8.459920000000        4.527180000000        2.418590000000        1.251290000000        0.643430000000        0.329180000000 28249600.000000000000  4250190.000000000000   975014.000000000000   277446.000000000000    90454.699999999997    32515.900000000001    12610.600000000000     5190.770000000000     2242.330000000000     1011.530000000000      475.547000000000      232.072000000000      116.874000000000       60.342700000000       31.524400000000       16.030800000000        8.459920000000        4.527180000000        2.418590000000        1.251290000000        0.643430000000        0.329180000000 28249600.000000000000  4250190.000000000000   975014.000000000000   277446.000000000000    90454.699999999997    32515.900000000001    12610.600000000000     5190.770000000000     2242.330000000000     1011.530000000000      475.547000000000      232.072000000000      116.874000000000       60.342700000000       31.524400000000       16.030800000000        8.459920000000        4.527180000000        2.418590000000        1.251290000000        0.643430000000        0.329180000000 28249600.000000000000  4250190.000000000000   975014.000000000000   277446.000000000000    90454.699999999997    32515.900000000001    12610.600000000000     5190.770000000000     2242.330000000000     1011.530000000000      475.547000000000      232.072000000000      116.874000000000       60.342700000000       31.524400000000       16.030800000000        8.459920000000        4.527180000000        2.418590000000        1.251290000000        0.643430000000        0.329180000000        0.142390000000        0.078190000000        0.037630000000        0.018290000000
 
        0.000000430000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000003290000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000017140000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000072280000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000265220000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000874840000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.002649910000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.007484470000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.019730930000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.047797990000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.103595620000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.192930180000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.286267570000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.292784940000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.163127980000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.032216880000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000592580000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001047900000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.000383790000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000157720000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.000143570000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000057700000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000000120000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000000960000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000004970000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000020990000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000077010000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000254310000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000771680000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.002190830000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.005835670000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.014468690000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.032803840000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.066744350000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.116686670000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.159197010000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.116206500000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.105470120000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.424834720000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.457797360000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.166199660000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.014623860000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.002046540000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000195190000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000040000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000330000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000001720000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000007240000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000026560000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000087720000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000266180000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000756220000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.002016180000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.005012030000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.011414850000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.023454260000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.041737840000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.058943050000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.045034190000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.044376180000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.218754490000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.363630430000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.154220680000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.352381520000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.614120990000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.300372750000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000000010000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000000080000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000000410000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000001730000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000006340000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000020940000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000063560000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000180560000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000481550000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.001197210000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.002728890000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.005611870000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.010013050000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.014190510000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.010921700000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.010863430000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.055014930000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.096882140000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.039479680000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.108669830000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.227283200000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.257084900000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
   406353.000000000000    13600.700000000001     3235.470000000000     1053.050000000000      403.569000000000      171.490000000000       78.236300000000       37.606500000000       18.709000000000        9.500410000000        4.905570000000        2.526700000000        1.271390000000        0.626010000000   406353.000000000000    13600.700000000001     3235.470000000000     1053.050000000000      403.569000000000      171.490000000000       78.236300000000       37.606500000000       18.709000000000        9.500410000000        4.905570000000        2.526700000000        1.271390000000        0.626010000000   406353.000000000000    13600.700000000001     3235.470000000000     1053.050000000000      403.569000000000      171.490000000000       78.236300000000       37.606500000000       18.709000000000        9.500410000000        4.905570000000        2.526700000000        1.271390000000        0.626010000000        0.300990000000        0.117690000000        0.051160000000        0.021420000000
 
        0.000000230000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000023930000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000212180000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001227330000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.005452770000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.019626690000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.058279930000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.139552990000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.255925620000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.339981320000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.273047740000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.096441480000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.009552310000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000675890000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000000070000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000007790000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000069080000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000400590000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.001784900000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.006483200000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.019562440000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.048247670000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.091286110000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.128420860000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.099522920000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.090123840000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.355198800000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.444488910000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000020000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000001620000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000014390000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000083540000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000372080000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.001353330000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.004086420000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.010110730000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.019167250000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.027161320000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.020807740000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.023085150000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.085510940000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.117944990000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       39.562800000000       11.437300000000        3.967430000000        1.524780000000        0.590470000000        0.219140000000        0.079570000000        0.028340000000
 
        0.003446000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.021360000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.075448000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.171528000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
        0.086000000000        0.258000000000        0.774100000000
 
        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000
 
        0.101200000000        0.302300000000
 
        1.000000000000        0.000000000000
        0.000000000000        1.000000000000
 
        0.253400000000
 
        1.000000000000
 
Ca:6-311G                
Pople's Gaussian basis set
 
    3
    0    1    2
    8    7    1
   14   11    3
 
   202699.000000000000    30382.500000000000     6915.080000000000     1959.020000000000      640.936000000000      233.977000000000       92.289200000000       37.254500000000        9.131980000000        3.817790000000        1.049350000000        0.428660000000        0.062822600000        0.026016200000
 
        0.000222964000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001729320000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.009002260000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.036669900000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.119410000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.291825000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.404415000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.296313000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
     1019.760000000000      241.596000000000       77.637000000000       29.115400000000       11.762600000000        4.922890000000        1.906450000000        0.736900000000        0.276420000000        0.060270000000        0.017910000000
 
        0.002059860000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.016650100000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.077764600000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.241806000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.432578000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.367325000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       15.080000000000        3.926000000000        1.233000000000
 
        0.036894700000
        0.177820000000
        0.425513000000
 
Ca:6-311G*               
Pople's Gaussian basis set
 
    3
    0    1    2
    8    7    2
   14   11    4
 
   202699.000000000000    30382.500000000000     6915.080000000000     1959.020000000000      640.936000000000      233.977000000000       92.289200000000       37.254500000000        9.131980000000        3.817790000000        1.049350000000        0.428660000000        0.062822600000        0.026016200000
 
        0.000222964000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001729320000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.009002260000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.036669900000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.119410000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.291825000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.404415000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.296313000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
     1019.760000000000      241.596000000000       77.637000000000       29.115400000000       11.762600000000        4.922890000000        1.906450000000        0.736900000000        0.276420000000        0.060270000000        0.017910000000
 
        0.002059860000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.016650100000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.077764600000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.241806000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.432578000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.367325000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       15.080000000000        3.926000000000        1.233000000000        0.260000000000
 
        0.036894700000        0.000000000000
        0.177820000000        0.000000000000
        0.425513000000        0.000000000000
        0.000000000000        1.000000000000
 
Ca:6-311+G*              
Pople's Gaussian basis set
 
    3
    0    1    2
    9    8    2
   15   12    4
 
   202699.000000000000    30382.500000000000     6915.080000000000     1959.020000000000      640.936000000000      233.977000000000       92.289200000000       37.254500000000        9.131980000000        3.817790000000        1.049350000000        0.428660000000        0.062822600000        0.026016200000        0.007100000000
 
        0.000222964000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001729320000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.009002260000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.036669900000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.119410000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.291825000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.404415000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.296313000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
     1019.760000000000      241.596000000000       77.637000000000       29.115400000000       11.762600000000        4.922890000000        1.906450000000        0.736900000000        0.276420000000        0.060270000000        0.017910000000        0.007100000000
 
        0.002059860000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.016650100000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.077764600000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.241806000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.432578000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.367325000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       15.080000000000        3.926000000000        1.233000000000        0.260000000000
 
        0.036894700000        0.000000000000
        0.177820000000        0.000000000000
        0.425513000000        0.000000000000
        0.000000000000        1.000000000000
 
Ca:def2-SV(P)            
Weigend and Ahlrichs' Gaussian basis set
 
    3
    0    1    2
    5    3    2
   14    9    4
 
    35138.713928999998     5276.411134800000     1200.469258900000      338.718105420000      109.853859220000       37.608880299000       73.107977555000        8.240770568800        3.295981299300        5.234180091400        0.841872205150        0.365102940290        0.051222402884        0.019825111408
 
        0.003948252074        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.030234243552        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.149520196810        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.515973457130        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        1.033951029600        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.769379335260        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.282685250110        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.679609214200        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.280376601600        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.007686860456        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.025382375978        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.016512171511        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
      413.113138930000       96.935786224000       30.372154659000       10.684776830000        3.882125835000        1.799301629500        0.691890565300        0.263640240960        0.074979000000
 
        0.020327135354        0.000000000000        0.000000000000
        0.147302763620        0.000000000000        0.000000000000
        0.548871673220        0.000000000000        0.000000000000
        1.044065981800        0.000000000000        0.000000000000
        0.686534906840        0.000000000000        0.000000000000
        0.000000000000        0.754102468710        0.000000000000
        0.000000000000        1.340929659900        0.000000000000
        0.000000000000        0.563919894350        0.000000000000
        0.000000000000        0.000000000000        1.000000000000
 
        5.497909387900        1.317712803200        0.321886826490        0.070528614919
 
        0.073770011433        0.000000000000
        0.260528531690        0.000000000000
        0.452338363800        0.000000000000
        0.000000000000        1.000000000000
 
Ca:def2-SVP              
Weigend and Ahlrichs' Gaussian basis set
 
    3
    0    1    2
    5    3    2
   14    9    4
 
    35138.713928999998     5276.411134800000     1200.469258900000      338.718105420000      109.853859220000       37.608880299000       73.107977555000        8.240770568800        3.295981299300        5.234180091400        0.841872205150        0.365102940290        0.051222402884        0.019825111408
 
        0.003948252074        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.030234243552        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.149520196810        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.515973457130        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        1.033951029600        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.769379335260        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.282685250110        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.679609214200        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.280376601600        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.007686860456        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.025382375978        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.016512171511        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
      413.113138930000       96.935786224000       30.372154659000       10.684776830000        3.882125835000        1.799301629500        0.691890565300        0.263640240960        0.074979000000
 
        0.020327135354        0.000000000000        0.000000000000
        0.147302763620        0.000000000000        0.000000000000
        0.548871673220        0.000000000000        0.000000000000
        1.044065981800        0.000000000000        0.000000000000
        0.686534906840        0.000000000000        0.000000000000
        0.000000000000        0.754102468710        0.000000000000
        0.000000000000        1.340929659900        0.000000000000
        0.000000000000        0.563919894350        0.000000000000
        0.000000000000        0.000000000000        1.000000000000
 
        5.497909387900        1.317712803200        0.321886826490        0.070528614919
 
        0.073770011433        0.000000000000
        0.260528531690        0.000000000000
        0.452338363800        0.000000000000
        0.000000000000        1.000000000000
 
Ca:def2-TZVP             
Weigend and Ahlrichs' Gaussian basis set
 
    3
    0    1    2
    6    5    3
   17   12    4
 
   172517.326850000012    25861.519274999999     5885.661866800000     1665.973003100000      542.367181480000      194.578034920000       75.303597636000       29.574062589000      191.200746600000       58.840299883000        8.964254084500        3.685696054100        5.246428972600        0.848626215280        0.367433005380        0.066821582613        0.026759730445
 
        0.000233175025        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001807652198        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.009394384426        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.038108409009        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.123312038530        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.290044709540        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.405871511570        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.203984107430        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.024419759759        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.115470274480        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.563566367170        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.567096827040        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.228253343250        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.726252191720        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
      836.972620580000      197.930401420000       63.135558054000       23.282687170000        9.117644493200        3.633612013900       13.494163120000        1.813925979000        0.719818260060        0.276295769920        0.074979000000        0.026927000000
 
        0.002525834609        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.020076506686        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.091302987366        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.252470299150        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.394263263440        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.230115594920        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.026495021951        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.550881082100        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.028061662000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
        5.497909387900        1.317712803200        0.321886826490        0.070528614919
 
        0.073770011433        0.000000000000        0.000000000000
        0.260528531690        0.000000000000        0.000000000000
        0.000000000000        0.452338363800        0.000000000000
        0.000000000000        0.000000000000        1.000000000000
 
Ca:def2-TZVPP            
Weigend and Ahlrichs' Gaussian basis set
 
    3
    0    1    2
    6    5    3
   17   12    4
 
   172517.326850000012    25861.519274999999     5885.661866800000     1665.973003100000      542.367181480000      194.578034920000       75.303597636000       29.574062589000      191.200746600000       58.840299883000        8.964254084500        3.685696054100        5.246428972600        0.848626215280        0.367433005380        0.066821582613        0.026759730445
 
        0.000233175025        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001807652198        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.009394384426        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.038108409009        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.123312038530        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.290044709540        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.405871511570        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.203984107430        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.024419759759        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.115470274480        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.563566367170        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.567096827040        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.228253343250        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.726252191720        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
      836.972620580000      197.930401420000       63.135558054000       23.282687170000        9.117644493200        3.633612013900       13.494163120000        1.813925979000        0.719818260060        0.276295769920        0.074979000000        0.026927000000
 
        0.002525834609        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.020076506686        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.091302987366        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.252470299150        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.394263263440        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.230115594920        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.026495021951        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.550881082100        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.028061662000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
        5.497909387900        1.317712803200        0.321886826490        0.070528614919
 
        0.073770011433        0.000000000000        0.000000000000
        0.260528531690        0.000000000000        0.000000000000
        0.000000000000        0.452338363800        0.000000000000
        0.000000000000        0.000000000000        1.000000000000
 
Ca:def2-QZVP             
Weigend and Ahlrichs' Gaussian basis set
 
    4
    0    1    2    3
   11    6    4    1
   24   18    6    1
 
  2433075.430399999954   364160.430149999971    82898.747636999993    23499.730540000000     7671.224598500000     2770.233068700000     1080.680755000000      448.048945310000      194.920077270000       88.039793338000       40.645696719000      779.533319180000      241.188563000000       92.403869324000       39.786090342000       18.195864278000        8.332145706700        3.919019620900        1.666709949300        0.808910849080        0.361741999340        0.082379874526        0.047947864375        0.022308112408
 
        0.000009162520        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000071271618        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000374337064        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001576286225        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.005702610258        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.018255738108        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.051906421035        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.127912385790        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.255866352310        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.360286782750        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.268384620200        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.018403005509        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.176494405440        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.776627995840        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -1.335215544400        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
     4064.223279600000      962.915506240000      312.345010460000      118.760560360000       49.816153133000       22.259679401000       10.286094124000        4.860698241600        2.252568294200       31.467555443000       10.657589056000        2.050555542600        0.943620892280        0.427090675040        0.177881872090        0.086000000000        0.041500000000        0.020000000000
 
        0.000197808910        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001730746590        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.009529872110        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.038387459783        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.116792562180        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.256372250970        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.379861937470        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.308057606370        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.085755999942        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.004244148748        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.019579425947        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.212375074220        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.462778711210        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.391774957280        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       16.924012098000        4.465540333000        1.434757620000        0.465523767840        0.140977110820        0.041467009281
 
        0.035543971560        0.000000000000        0.000000000000        0.000000000000
        0.181336983350        0.000000000000        0.000000000000        0.000000000000
        0.480020601160        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
        0.321000000000
 
        1.000000000000
 
Ca:def2-QZVPP            
Weigend and Ahlrichs' Gaussian basis set
 
    4
    0    1    2    3
   11    6    4    3
   24   18    6    3
 
  2433075.430399999954   364160.430149999971    82898.747636999993    23499.730540000000     7671.224598500000     2770.233068700000     1080.680755000000      448.048945310000      194.920077270000       88.039793338000       40.645696719000      779.533319180000      241.188563000000       92.403869324000       39.786090342000       18.195864278000        8.332145706700        3.919019620900        1.666709949300        0.808910849080        0.361741999340        0.082379874526        0.047947864375        0.022308112408
 
        0.000009162520        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000071271618        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000374337064        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001576286225        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.005702610258        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.018255738108        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.051906421035        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.127912385790        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.255866352310        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.360286782750        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.268384620200        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.018403005509        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.176494405440        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.776627995840        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -1.335215544400        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
     4064.223279600000      962.915506240000      312.345010460000      118.760560360000       49.816153133000       22.259679401000       10.286094124000        4.860698241600        2.252568294200       31.467555443000       10.657589056000        2.050555542600        0.943620892280        0.427090675040        0.177881872090        0.086000000000        0.041500000000        0.020000000000
 
        0.000197808910        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001730746590        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.009529872110        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.038387459783        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.116792562180        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.256372250970        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.379861937470        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.308057606370        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.085755999942        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.004244148748        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.019579425947        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.212375074220        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.462778711210        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.391774957280        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       16.924012098000        4.465540333000        1.434757620000        0.465523767840        0.140977110820        0.041467009281
 
        0.035543971560        0.000000000000        0.000000000000        0.000000000000
        0.181336983350        0.000000000000        0.000000000000        0.000000000000
        0.480020601160        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
        2.650000000000        0.794000000000        0.130000000000
 
        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000
 
Ca:cc-pVDZ-RI            
Weigend's auxiliary basis set
 
    3
    0    1    2
    5    4    2
   53   31    5
 
   190000.700000000012    28481.459999999999     6482.701000000000     1835.891000000000      598.724300000000      215.884100000000       84.012420000000       34.224880000000       10.024970000000        4.055920000000        1.020261000000        0.426865000000        0.063347000000   190000.700000000012    28481.459999999999     6482.701000000000     1835.891000000000      598.724300000000      215.884100000000       84.012420000000       34.224880000000       10.024970000000        4.055920000000        1.020261000000        0.426865000000        0.063347000000   190000.700000000012    28481.459999999999     6482.701000000000     1835.891000000000      598.724300000000      215.884100000000       84.012420000000       34.224880000000       10.024970000000        4.055920000000        1.020261000000        0.426865000000        0.063347000000   190000.700000000012    28481.459999999999     6482.701000000000     1835.891000000000      598.724300000000      215.884100000000       84.012420000000       34.224880000000       10.024970000000        4.055920000000        1.020261000000        0.426865000000        0.063347000000        0.026301000000
 
        0.000221450000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001718300000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.008923480000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.036301830000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.117622230000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.286043520000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.422607080000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.257743660000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.023918930000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.004952180000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001717790000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.000892090000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000245100000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000064530000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000496620000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.002628260000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.010668450000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.037135090000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.098042840000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.203426920000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.152446550000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.482794060000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.629238390000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.061648420000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.014799710000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.003610890000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000022230000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000171700000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000904520000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.003703430000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.012837500000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.034754590000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.073034910000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.061000830000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.242929280000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.487085000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.565028040000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.655743860000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.026728940000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000005310000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000041110000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000215680000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000888270000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.003058130000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.008376080000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.017410560000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.015154530000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.062079190000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.126118030000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.173606940000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.378229430000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.659646980000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
     1072.043000000000      253.843900000000       81.316260000000       30.241830000000       12.101100000000        5.022554000000        1.909220000000        0.771304000000        0.300570000000        0.076649000000     1072.043000000000      253.843900000000       81.316260000000       30.241830000000       12.101100000000        5.022554000000        1.909220000000        0.771304000000        0.300570000000        0.076649000000     1072.043000000000      253.843900000000       81.316260000000       30.241830000000       12.101100000000        5.022554000000        1.909220000000        0.771304000000        0.300570000000        0.076649000000        0.027772000000
 
        0.001981660000        0.000000000000        0.000000000000        0.000000000000
        0.016129440000        0.000000000000        0.000000000000        0.000000000000
        0.076578510000        0.000000000000        0.000000000000        0.000000000000
        0.232695940000        0.000000000000        0.000000000000        0.000000000000
        0.424452100000        0.000000000000        0.000000000000        0.000000000000
        0.373264020000        0.000000000000        0.000000000000        0.000000000000
        0.078685300000        0.000000000000        0.000000000000        0.000000000000
       -0.005999270000        0.000000000000        0.000000000000        0.000000000000
        0.002642570000        0.000000000000        0.000000000000        0.000000000000
       -0.000856940000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000648910000        0.000000000000        0.000000000000
        0.000000000000       -0.005279070000        0.000000000000        0.000000000000
        0.000000000000       -0.025811310000        0.000000000000        0.000000000000
        0.000000000000       -0.080628920000        0.000000000000        0.000000000000
        0.000000000000       -0.158465520000        0.000000000000        0.000000000000
        0.000000000000       -0.128168160000        0.000000000000        0.000000000000
        0.000000000000        0.256101030000        0.000000000000        0.000000000000
        0.000000000000        0.587240680000        0.000000000000        0.000000000000
        0.000000000000        0.303725610000        0.000000000000        0.000000000000
        0.000000000000        0.014164510000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000135950000        0.000000000000
        0.000000000000        0.000000000000        0.001094200000        0.000000000000
        0.000000000000        0.000000000000        0.005426800000        0.000000000000
        0.000000000000        0.000000000000        0.016747180000        0.000000000000
        0.000000000000        0.000000000000        0.033898630000        0.000000000000
        0.000000000000        0.000000000000        0.025311830000        0.000000000000
        0.000000000000        0.000000000000       -0.058957130000        0.000000000000
        0.000000000000        0.000000000000       -0.158761200000        0.000000000000
        0.000000000000        0.000000000000       -0.085545230000        0.000000000000
        0.000000000000        0.000000000000        0.544646650000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       10.318200000000        2.592420000000        0.761700000000        0.208380000000        0.053700000000
 
        0.032849000000        0.000000000000
        0.148192000000        0.000000000000
        0.310921000000        0.000000000000
        0.452195000000        0.000000000000
        0.000000000000        1.000000000000
 
Ca:cc-pVTZ-RI            
Weigend's auxiliary basis set
 
    4
    0    1    2    3
    6    5    3    1
   74   38    6    1
 
  2402654.000000000000   359789.799999999988    81878.089999999997    23190.889999999999     7565.212000000000     2730.702000000000     1064.640000000000      441.060500000000      191.726900000000       86.537740000000       39.899240000000       17.640650000000        8.359990000000        3.951330000000        1.713400000000        0.810860000000        0.360250000000        0.044840000000  2402654.000000000000   359789.799999999988    81878.089999999997    23190.889999999999     7565.212000000000     2730.702000000000     1064.640000000000      441.060500000000      191.726900000000       86.537740000000       39.899240000000       17.640650000000        8.359990000000        3.951330000000        1.713400000000        0.810860000000        0.360250000000        0.044840000000  2402654.000000000000   359789.799999999988    81878.089999999997    23190.889999999999     7565.212000000000     2730.702000000000     1064.640000000000      441.060500000000      191.726900000000       86.537740000000       39.899240000000       17.640650000000        8.359990000000        3.951330000000        1.713400000000        0.810860000000        0.360250000000        0.044840000000  2402654.000000000000   359789.799999999988    81878.089999999997    23190.889999999999     7565.212000000000     2730.702000000000     1064.640000000000      441.060500000000      191.726900000000       86.537740000000       39.899240000000       17.640650000000        8.359990000000        3.951330000000        1.713400000000        0.810860000000        0.360250000000        0.044840000000        0.081080000000        0.021430000000
 
        0.000009310000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000072390000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000380590000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001604530000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.005807800000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.018595660000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.052877760000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.130151490000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.259314710000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.361496100000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.264111600000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.057093980000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.001822000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.002111640000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.000977090000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000455810000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.000191460000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.000078740000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000002700000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000021020000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000110520000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000466660000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.001695130000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.005483460000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.015965970000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.041513840000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.092863870000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.165316570000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.176640740000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.064444220000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.510879620000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.494638040000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.087500940000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.003591010000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.002492200000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000645870000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000930000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000007250000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000038110000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000161010000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000584660000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.001895040000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.005525250000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.014470100000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.032715810000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.060031900000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.067016830000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.025936600000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.267474670000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.426972560000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.067964050000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.710205390000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.441800570000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.011869240000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000000220000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000001730000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000009100000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000038440000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000139650000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000452510000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.001320380000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.003458410000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.007836860000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.014415170000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.016216480000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.006344200000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.067406260000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.114473960000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.026344770000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.233698850000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.316075380000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.561110350000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
     4061.289000000000      962.246500000000      312.168600000000      118.714400000000       49.806700000000       22.259980000000       10.287640000000        4.861154000000        2.248773000000        1.033662000000        0.464132000000        0.067390000000     4061.289000000000      962.246500000000      312.168600000000      118.714400000000       49.806700000000       22.259980000000       10.287640000000        4.861154000000        2.248773000000        1.033662000000        0.464132000000        0.067390000000     4061.289000000000      962.246500000000      312.168600000000      118.714400000000       49.806700000000       22.259980000000       10.287640000000        4.861154000000        2.248773000000        1.033662000000        0.464132000000        0.067390000000        0.198750000000        0.025420000000
 
        0.000197990000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001732080000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.009533790000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.038390120000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.116758810000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.256268740000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.379780800000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.308293260000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.085920900000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.002120670000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001288800000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000147280000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000064550000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000564580000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.003131250000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.012740860000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.039914030000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.090504480000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.142618980000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.109809040000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.151624900000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.461764110000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.432600310000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.002528740000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000013360000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000118520000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000648720000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.002679930000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.008285130000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.019212350000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.029549840000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.024312320000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.041112300000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.104197580000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.150365370000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.598611640000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       16.946230000000        4.472120000000        1.438090000000        0.466990000000        0.141510000000        0.041640000000
 
        0.015473000000        0.000000000000        0.000000000000
        0.078874000000        0.000000000000        0.000000000000
        0.208780000000        0.000000000000        0.000000000000
        0.330213000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000
 
        0.150900000000
 
        1.000000000000
 
Ca:cc-pVQZ-RI            
Weigend's auxiliary basis set
 
    5
    0    1    2    3    4
    7    6    4    2    1
   79   42    7    2    1
 
  7503960.000000000000  1123486.000000000000   255663.500000000000    72416.059999999998    23626.040000000001     8529.986000000001     3327.341000000000     1380.354000000000      602.214900000000      273.887400000000      128.945100000000       62.422990000000       30.574370000000       13.855220000000        6.836204000000        3.378153000000        1.491907000000        0.721140000000        0.334152000000  7503960.000000000000  1123486.000000000000   255663.500000000000    72416.059999999998    23626.040000000001     8529.986000000001     3327.341000000000     1380.354000000000      602.214900000000      273.887400000000      128.945100000000       62.422990000000       30.574370000000       13.855220000000        6.836204000000        3.378153000000        1.491907000000        0.721140000000        0.334152000000  7503960.000000000000  1123486.000000000000   255663.500000000000    72416.059999999998    23626.040000000001     8529.986000000001     3327.341000000000     1380.354000000000      602.214900000000      273.887400000000      128.945100000000       62.422990000000       30.574370000000       13.855220000000        6.836204000000        3.378153000000        1.491907000000        0.721140000000        0.334152000000  7503960.000000000000  1123486.000000000000   255663.500000000000    72416.059999999998    23626.040000000001     8529.986000000001     3327.341000000000     1380.354000000000      602.214900000000      273.887400000000      128.945100000000       62.422990000000       30.574370000000       13.855220000000        6.836204000000        3.378153000000        1.491907000000        0.721140000000        0.334152000000        0.082382000000        0.041655000000        0.019973000000
 
        0.000002240000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000017440000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000091770000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000387680000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001411850000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.004593590000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.013597330000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.036673600000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.088720760000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.184148930000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.300742160000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.324348150000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.171957470000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.024809330000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.001034080000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001012900000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.000466780000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000186620000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.000088080000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000000650000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000005070000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000026630000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000112660000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000410300000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.001341110000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.003994040000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.010989030000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.027564470000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.062162460000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.118604760000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.174104940000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.118477140000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.194574680000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.546611310000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.381263240000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.051878530000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.002049960000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.001688090000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000220000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000001750000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000009180000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000038880000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000141380000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000463240000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.001377310000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.003807860000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.009556410000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.021831320000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.042149510000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.064628450000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.045359830000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.082498530000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.323151070000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.360634960000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.204389540000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.696100890000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.361774980000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000000050000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000000420000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000002190000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000009290000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000033740000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000110700000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000328620000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000910500000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.002280900000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.005230950000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.010083610000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.015612940000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.010883380000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.019957680000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.083488600000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.095949510000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.063957720000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.245224870000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.285846700000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
     9363.010000000000     2216.255000000000      719.759600000000      275.172800000000      116.392400000000       52.777700000000       25.131880000000       12.314160000000        6.166797000000        3.114279000000        1.519013000000        0.725435000000        0.340926000000     9363.010000000000     2216.255000000000      719.759600000000      275.172800000000      116.392400000000       52.777700000000       25.131880000000       12.314160000000        6.166797000000        3.114279000000        1.519013000000        0.725435000000        0.340926000000     9363.010000000000     2216.255000000000      719.759600000000      275.172800000000      116.392400000000       52.777700000000       25.131880000000       12.314160000000        6.166797000000        3.114279000000        1.519013000000        0.725435000000        0.340926000000        0.144000000000        0.058000000000        0.023160000000
 
        0.000046170000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000410490000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.002355670000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.010254910000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.035660350000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.099640560000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.213206260000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.331535240000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.329342630000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.154664140000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.022155260000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000551910000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000151770000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000015050000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000133610000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000770140000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.003364530000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.011866240000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.033894230000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.075143290000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.121443480000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.129220840000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.015877030000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.308536760000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.472815210000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.294102810000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000003130000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000027950000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000160030000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000704170000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.002469220000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.007118990000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.015690170000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.025785640000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.026936560000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.004855860000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.076542120000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.115544590000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.121270620000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       26.270830000000        7.307820000000        2.454980000000        0.887140000000        0.309250000000        0.103160000000        0.033740000000
 
        0.007346000000        0.000000000000        0.000000000000        0.000000000000
        0.040901000000        0.000000000000        0.000000000000        0.000000000000
        0.130065000000        0.000000000000        0.000000000000        0.000000000000
        0.244151000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
        0.488300000000        0.116500000000
 
        1.000000000000        0.000000000000
        0.000000000000        1.000000000000
 
        0.146600000000
 
        1.000000000000
 
Ca:cc-pV5Z-RI            
Weigend's auxiliary basis set
 
    6
    0    1    2    3    4    5
    8    7    5    3    2    1
   92   46    8    3    2    1
 
 28249600.000000000000  4250190.000000000000   975014.000000000000   277446.000000000000    90454.699999999997    32515.900000000001    12610.600000000000     5190.770000000000     2242.330000000000     1011.530000000000      475.547000000000      232.072000000000      116.874000000000       60.342700000000       31.524400000000       16.030800000000        8.459920000000        4.527180000000        2.418590000000        1.251290000000        0.643430000000        0.329180000000 28249600.000000000000  4250190.000000000000   975014.000000000000   277446.000000000000    90454.699999999997    32515.900000000001    12610.600000000000     5190.770000000000     2242.330000000000     1011.530000000000      475.547000000000      232.072000000000      116.874000000000       60.342700000000       31.524400000000       16.030800000000        8.459920000000        4.527180000000        2.418590000000        1.251290000000        0.643430000000        0.329180000000 28249600.000000000000  4250190.000000000000   975014.000000000000   277446.000000000000    90454.699999999997    32515.900000000001    12610.600000000000     5190.770000000000     2242.330000000000     1011.530000000000      475.547000000000      232.072000000000      116.874000000000       60.342700000000       31.524400000000       16.030800000000        8.459920000000        4.527180000000        2.418590000000        1.251290000000        0.643430000000        0.329180000000 28249600.000000000000  4250190.000000000000   975014.000000000000   277446.000000000000    90454.699999999997    32515.900000000001    12610.600000000000     5190.770000000000     2242.330000000000     1011.530000000000      475.547000000000      232.072000000000      116.874000000000       60.342700000000       31.524400000000       16.030800000000        8.459920000000        4.527180000000        2.418590000000        1.251290000000        0.643430000000        0.329180000000        0.142390000000        0.078190000000        0.037630000000        0.018290000000
 
        0.000000430000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000003290000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000017140000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000072280000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000265220000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000874840000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.002649910000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.007484470000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.019730930000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.047797990000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.103595620000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.192930180000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.286267570000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.292784940000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.163127980000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.032216880000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000592580000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001047900000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.000383790000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000157720000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -0.000143570000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000057700000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000000120000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000000960000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000004970000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000020990000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000077010000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000254310000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000771680000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.002190830000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.005835670000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.014468690000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.032803840000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.066744350000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.116686670000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.159197010000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.116206500000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.105470120000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.424834720000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.457797360000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.166199660000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.014623860000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.002046540000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000195190000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000040000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000330000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000001720000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000007240000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000026560000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000087720000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000266180000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000756220000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.002016180000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.005012030000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.011414850000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.023454260000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.041737840000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.058943050000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.045034190000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.044376180000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.218754490000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.363630430000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.154220680000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.352381520000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.614120990000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.300372750000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000000010000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000000080000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000000410000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000001730000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000006340000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000020940000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000063560000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000180560000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.000481550000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.001197210000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.002728890000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.005611870000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.010013050000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.014190510000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.010921700000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.010863430000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.055014930000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.096882140000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.039479680000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.108669830000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.227283200000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000       -0.257084900000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
   406353.000000000000    13600.700000000001     3235.470000000000     1053.050000000000      403.569000000000      171.490000000000       78.236300000000       37.606500000000       18.709000000000        9.500410000000        4.905570000000        2.526700000000        1.271390000000        0.626010000000   406353.000000000000    13600.700000000001     3235.470000000000     1053.050000000000      403.569000000000      171.490000000000       78.236300000000       37.606500000000       18.709000000000        9.500410000000        4.905570000000        2.526700000000        1.271390000000        0.626010000000   406353.000000000000    13600.700000000001     3235.470000000000     1053.050000000000      403.569000000000      171.490000000000       78.236300000000       37.606500000000       18.709000000000        9.500410000000        4.905570000000        2.526700000000        1.271390000000        0.626010000000        0.300990000000        0.117690000000        0.051160000000        0.021420000000
 
        0.000000230000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000023930000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000212180000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.001227330000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.005452770000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.019626690000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.058279930000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.139552990000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.255925620000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.339981320000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.273047740000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.096441480000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.009552310000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000675890000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000000070000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000007790000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000069080000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.000400590000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.001784900000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.006483200000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.019562440000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.048247670000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.091286110000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.128420860000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.099522920000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.090123840000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.355198800000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.444488910000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000020000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000001620000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000014390000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000083540000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000372080000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.001353330000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.004086420000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.010110730000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.019167250000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.027161320000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.020807740000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.023085150000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.085510940000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000       -0.117944990000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       39.562800000000       11.437300000000        3.967430000000        1.524780000000        0.590470000000        0.219140000000        0.079570000000        0.028340000000
 
        0.003446000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.021360000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.075448000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.171528000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
        0.086000000000        0.258000000000        0.774100000000
 
        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000
 
        0.101200000000        0.302300000000
 
        1.000000000000        0.000000000000
        0.000000000000        1.000000000000
 
        0.253400000000
 
        1.000000000000
 
Ca:def2-SV(P)-RI         
Weigend's auxiliary basis set
 
    4
    0    1    2    3
    8    8    6    2
   11    8    6    2
 
       84.490299430000       34.331564080000       15.849273960000        6.783367490000        2.157679120000        1.175412940000        0.640315590000        0.348817040000        0.190020870000        0.098513550000        0.057932160000
 
       -0.860233610000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        1.320002700000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        1.095966730000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -1.792479000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       17.157940518000        7.117941160900        2.533974866400        1.399444350700        0.829386024910        0.317878690000        0.121006760330        0.058498883518
 
        1.001288700000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -1.178460970000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.585499080000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.391855630000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       35.598641680000        9.959682340600        2.116683288300        0.901926249850        0.352047695520        0.113072297950
 
        1.077489660000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.278960950000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.694980830000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000       -0.089306030000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
        2.113860760900        0.747985214070
 
        1.000000000000        0.000000000000
        0.000000000000        1.000000000000
 
Ca:def2-SVP-RI           
Weigend's auxiliary basis set
 
    4
    0    1    2    3
    8    8    6    2
   11    8    6    2
 
       84.490299430000       34.331564080000       15.849273960000        6.783367490000        2.157679120000        1.175412940000        0.640315590000        0.348817040000        0.190020870000        0.098513550000        0.057932160000
 
       -0.860233610000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        1.320002700000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        1.095966730000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
       -1.792479000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       17.157940518000        7.117941160900        2.533974866400        1.399444350700        0.829386024910        0.317878690000        0.121006760330        0.058498883518
 
        1.001288700000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -1.178460970000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.585499080000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.391855630000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       35.598641680000        9.959682340600        2.116683288300        0.901926249850        0.352047695520        0.113072297950
 
        1.077489660000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000       -0.278960950000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.694980830000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000       -0.089306030000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
        2.113860760900        0.747985214070
 
        1.000000000000        0.000000000000
        0.000000000000        1.000000000000
 
Ca:def2-TZVP-RI          
Weigend's auxiliary basis set
 
    4
    0    1    2    3
   11    8    7    5
   11    8    7    5
 
       84.490300000000       34.331600000000       15.849300000000        6.783370000000        2.157680000000        1.175410000000        0.640316000000        0.348817000000        0.190021000000        0.098513600000        0.057932200000
 
        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       17.142900000000        7.124410000000        2.524980000000        1.399470000000        0.815390000000        0.317879000000        0.126217000000        0.059367300000
 
        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       48.481400000000       17.722900000000        8.880560000000        2.156780000000        0.821329000000        0.385113000000        0.114870000000
 
        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       24.658300000000        2.877690000000        1.393500000000        0.775054000000        0.357715000000
 
        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
Ca:def2-TZVPP-RI         
Weigend's auxiliary basis set
 
    4
    0    1    2    3
   11    8    7    5
   11    8    7    5
 
       84.490300000000       34.331600000000       15.849300000000        6.783370000000        2.157680000000        1.175410000000        0.640316000000        0.348817000000        0.190021000000        0.098513600000        0.057932200000
 
        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       17.142900000000        7.124410000000        2.524980000000        1.399470000000        0.815390000000        0.317879000000        0.126217000000        0.059367300000
 
        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       48.481400000000       17.722900000000        8.880560000000        2.156780000000        0.821329000000        0.385113000000        0.114870000000
 
        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       24.658300000000        2.877690000000        1.393500000000        0.775054000000        0.357715000000
 
        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
Ca:def2-QZVP-RI          
Weigend's auxiliary basis set
 
    5
    0    1    2    3    4
   14   13    9    8    5
   14   13    9    8    5
 
     1090.370000000000      160.219000000000       71.713100000000       28.986900000000       13.546700000000        7.504220000000        5.310350000000        2.723590000000        1.437750000000        0.694726000000        0.392688000000        0.161123000000        0.083347200000        0.045612200000
 
        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       87.516500000000       46.795300000000       21.840700000000        8.602000000000        4.829160000000        2.709010000000        1.624690000000        0.755232000000        0.414473000000        0.227464000000        0.135045000000        0.077821400000        0.050202000000
 
        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       52.362500000000       14.927900000000        7.235940000000        2.602920000000        1.189240000000        0.702372000000        0.391080000000        0.200618000000        0.077243600000
 
        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       22.932700000000        7.399040000000        3.379310000000        1.666330000000        0.957480000000        0.488917000000        0.183017000000        0.100856000000
 
        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       11.805700000000        3.638960000000        1.466110000000        0.567267000000        0.263661000000
 
        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
Ca:def2-QZVPP-RI         
Weigend's auxiliary basis set
 
    5
    0    1    2    3    4
   14   13    9    8    5
   14   13    9    8    5
 
     1090.370000000000      160.219000000000       71.713100000000       28.986900000000       13.546700000000        7.504220000000        5.310350000000        2.723590000000        1.437750000000        0.694726000000        0.392688000000        0.161123000000        0.083347200000        0.045612200000
 
        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       87.516500000000       46.795300000000       21.840700000000        8.602000000000        4.829160000000        2.709010000000        1.624690000000        0.755232000000        0.414473000000        0.227464000000        0.135045000000        0.077821400000        0.050202000000
 
        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       52.362500000000       14.927900000000        7.235940000000        2.602920000000        1.189240000000        0.702372000000        0.391080000000        0.200618000000        0.077243600000
 
        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       22.932700000000        7.399040000000        3.379310000000        1.666330000000        0.957480000000        0.488917000000        0.183017000000        0.100856000000
 
        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       11.805700000000        3.638960000000        1.466110000000        0.567267000000        0.263661000000
 
        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
Ca:def2-QZVPP-RI-JK      
Weigend's Coulomb/exchange fitting basis set
 
    5
    0    1    2    3    4
   15   11   10    5    3
   18   14   12    5    3
 
     8607.040797000000     2377.111446900000     1016.799637600000      426.247959400000      186.676116400000       85.428409300000       40.959701100000       20.206722100000        9.428330400000        5.510572600000        3.028313700000        1.713981700000        0.995281700000        0.590490800000        0.356349300000        0.217720600000        0.135360800000        0.084369500000
 
        0.093304673100        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.221634723400        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.490301779600        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.837720987100        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
     1138.808687400000      474.015973700000      202.998775000000       89.287994000000       40.258820000000       18.569298900000        8.742302600000        4.190985000000        2.040657200000        1.006554600000        0.501558200000        0.251760600000        0.126933100000        0.064092100000
 
        0.104922455500        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.250632791700        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.651720760500        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.708120422300        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
      272.636164700000      113.761371100000       49.089723300000       21.850638400000       10.004316700000        4.696929700000        2.253644100000        1.101133000000        0.545790600000        0.273350000000        0.137765000000        0.069577900000
 
        0.103337047400        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.367822410500        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.924136423400        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
       20.718704800000        6.589751600000        2.105441400000        0.716749300000        0.263296900000
 
        0.783579656700        0.000000000000        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.621291333900        0.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        0.000000000000        0.000000000000        1.000000000000
 
        7.174917000000        2.391639000000        0.797213000000
 
        1.000000000000        0.000000000000        0.000000000000
        0.000000000000        1.000000000000        0.000000000000
        0.000000000000        0.000000000000        1.000000000000
 
